N-(3-Chlorophenyl)-4-methylbenzamide hemihydrate
نویسندگان
چکیده
In the title compound, C(14)H(12)ClNO·0.5H(2)O, the water mol-ecule is located on a twofold axis of symmetry. The meta-Cl atom in the aniline ring is positioned anti to the N-H bond. The two benzene rings make a dihedral angle of 40.40 (11)°. The crystal structure is stabilized by inter-molecular N-H⋯O and O-H⋯O hydrogen bonds, which link the mol-ecules into chains along the a axis.
منابع مشابه
N-(3-Chlorophenyl)-3-methylbenzamide hemihydrate
In the title compound, C(14)H(12)ClNO·0.5H(2)O, the N-H bond is in an anti conformation to the C=O bond. The two aromatic rings make a dihedral angle of 49.5 (1)°. The water mol-ecule lies on a twofold rotation axis. In the crystal, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds connect the mol-ecules into a three-dimensional network.
متن کاملN-(4-Chlorophenyl)-4-methylbenzamide
In the title compound, C(14)H(12)ClNO, the aromatic rings make a dihedral angle of 59.25 (5)°. The methyl group is disordered over two equally occupied positions. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into infinite C(4) chains running along the a axis.
متن کاملN-(2-Chlorophenyl)-3-methylbenzamide
In the title compound, C(14)H(12)ClNO, the N-H bond is anti to the carbonyl bond and the two aromatic rings make a dihedral angle of 5.4 (2)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds connect the mol-ecules into chains running along the b axis. The chains are inter-connected through short Cl⋯Cl contacts [3.279 (1) Å].
متن کاملN-(2-Chlorophenyl)-4-methylbenzamide
The asymmetric unit of the title compound, C(14)H(12)ClNO, contains two independent mol-ecules in which the dihedral angles between the two aromatic rings are 51.76 (6) and 51.48 (7)°. The crystal structure is stabilized by inter-molecular N-H⋯O hydrogen bonds, which link the mol-ecules into chains running along the c axis.
متن کامل4-Chloroanilinium (4-chlorophenyl)guanidinium dichloride hemihydrate
In the title hydrated molecular salt, C(6)H(7)ClN(+)·C(7)H(9)ClN(3) (+)·2Cl(-)·0.5H(2)O, the water O atom lies on a crystallographic twofold axis. In the crystal, inter-molecular N-H⋯Cl and O-H⋯Cl hydrogen bonds form layers perpendicular to the ac plane in which both the water mol-ecule and the chloride anion are involved in connecting the layers into a three-dimensional structure.
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